mechanism of ozonolysis of naphthalene

The rearrangement of the molozonide is exothermic. Philip Sigmon Bailey, John E. Batterbee, Allen G. Lane. In this case, the methanal by-product is a gas that escapes from the solution and does not contaminate the bicyclic ketone product. The present commercial processes are complicated, labor-intensive and associated with the formation of highly toxic wastes. Nevertheless, the method proves useful in specific cases, such as the oxidative cleavage of α-pinene. ), an explosive and unstable ozonide is formed. Guancong Huang, Ying Liu, Min Shao, Yue Li, Qi Chen, Yan Zheng, Zhijun Wu, Yuechen Liu, Yusheng Wu, Min Hu, Xin Li, Sihua Lu, Chenjing Wang, Junyi Liu, Mei Zheng. Enter your email address below and we will send you your username, If the address matches an existing account you will receive an email with instructions to retrieve your username, I have read and accept the Wiley Online Library Terms and Conditions of Use. The decomposition products to be expected have all been found and identified. 7 … Kinetics and Products of Photolysis and Reaction with OH Radicals of a Series of Aromatic Carbonyl Compounds. 121 publications. https://doi.org/10.1021/ba-1968-0077.ch065, https://doi.org/10.1080/01919510108962000, https://doi.org/10.1016/0043-1354(86)90009-6, https://doi.org/10.1016/S0040-4039(01)90214-X, https://doi.org/10.1016/B978-0-12-073102-2.50021-5, https://doi.org/10.1016/B978-0-12-073101-5.50021-4, https://doi.org/10.1007/978-1-4899-5241-7_1, https://doi.org/10.1016/S0065-2725(08)60607-8. Find more information about Crossref citation counts. You’ve supercharged your research process with ACS and Mendeley!

A theoretical investigation. A theoretical study. The reaction of the unsaturated cyclo-pentafused ring with O3 is the dominant pathway. Ned. A Review on Reactions of Polycyclic Aromatic Hydrocarbons with the Most Abundant Atmospheric Chemical Fragments: Theoretical and Experimental Data. This article is cited by Figure 3. Get article recommendations from ACS based on references in your Mendeley library. The full text of this article hosted at iucr.org is unavailable due to technical difficulties. The atmospheric oxidation mechanism of 2-methylnaphthalene. Unique products from the reaction of naphthalene with the hydroxyl radical. A. CRIEGEE MECHANISM: NATURE OF PEROXIDIC OZONOLYSIS PRODUCTS 1. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. From the compounds formed upon ozonolysis of 2,3‐dimethylnaphthalene it follows that upon the action of ozone on 2,3‐dimethylnaphthalene two isomeric diozonides are formed; in one diozonide (main product) the O3 groups are bound in the methylated six‐membered ring, the other diozonide (by‐product) contains the O3 groups in the non‐methylated six‐membered ring. Since the remaining fractions were more polar, they were derivatized with Tri-Sil Concentrate, BSA, or Methyl-8. We use cookies to help provide and enhance our service and tailor content and ads. Chunli Yan, Jingwen Chen, Liping Huang, Guanghui Ding, Xiaoying Huang. The atmospheric lifetime of Ary determined by O3 is about 0.75 h. The rate constants of the crucial elementary steps were evaluated. Taija Rissanen, Tuulia Hyötyläinen, Minna Kallio, Juhani Kronholm, Markku Kulmala, Marja-Liisa Riekkola. This step requires a total of three electron pair shifts, as shown below. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. First, an unstable intermediate, called a molozonide, forms by a cyclic concerted addition of the terminal oxygen atoms of ozone to the π bond of the alkene. Influence of applied voltage waveforms on the performance of surface dielectric barrier discharge reactor for decomposition of naphthalene.

α Polycyclic aromatic hydrocarbons and their oxygenated derivatives in the urban atmosphere of Athens.

S. A. Benner, K. G. Devine, L. N. Matveeva, D. H. Powell. Get article recommendations from ACS based on references in your Mendeley library. Find more information on the Altmetric Attention Score and how the score is calculated. Dicarbonyl Products of the OH Radical-Initiated Reactions of Naphthalene and the C1- and C2-Alkylnaphthalenes.

Lane, Jong Bae Heo, Seung-Muk Yi, Yong Pyo Kim.

-dicarbonyls in aerosols at Gosan, Jeju Island, South Korea: Implications for sources, formation, and degradation during long-range transport. J. K. E. Kautzman, J. D. Surratt, M. N. Chan, A. W. H. Chan, S. P. Hersey, P. S. Chhabra, N. F. Dalleska, P. O. Wennberg, R. C. Flagan and J. H. Seinfeld .

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.



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